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Compounds 1a– d, 2, and 3 were prepared from 7a– 7d, 8 and 9, respectively, by the tBuOK-mediated oxidative dehydrogenation. The reaction conditions were substrate dependent. For details, see Supplementary Information. Characterization Ranzen, V. & Joschek, H.-I. Zum Radikalcharakter des Bis-Dibenzo[ a. i]Fluorenylidens. Justus Liebigs Ann. Chem. 648, 63–68 (1961).
Twisted Bonds | Cora Reilly
Nino swiped his thumb over my pulse point. “Life doesn’t work like that. Bad things are not fate, or punishment of an almighty power. Sometimes bad things just happen.” Dormann, E. et al. Benzobisdithiazole (BBDT): An electron spin resonance study. J. Am. Chem. Soc. 109, 2594–2599 (1987). Kubo, T. et al. Synthesis, Intermolecular interaction, and semiconductive behavior of a delocalized singlet biradical hydrocarbon. Angew. Chem. Int. Ed. 44, 6564–6568 (2005).Saltiel, J. & Charlton, J. L. Cis-trans isomerization of olefins in Rearrangements in Ground and Excited States (ed. de Mayo, P.), Vol. 3, 25–89 (Academic Press, New York, 1980). I shrugged. “I know that now, or I think I do. But when I was a young girl, Father always blamed me or Mother when something went wrong, and so did my brothers even when they had messed up, and I believed them. If you’re told something often enough, you just take it for the truth. When Father hit me, I thought I deserved it.” I’m just happy. For a while I thought it was something about me, something inherently wrong with me, why I couldn’t be happy, why bad things kept happening to me.”
These Twisted Bonds by Lexi Ryan | Waterstones These Twisted Bonds by Lexi Ryan | Waterstones
Xu, X. et al. 6,6′-Biindeno[1,2‑ b]anthracene: An open-shell biaryl with high diradical character. J. Am. Chem. Soc. 145, 3891–3896 (2023). Did your brothers ever hit you like your father did?” Nino asked, throwing me off with the change of topic.Ni, Y. et al. A Chichibabin’s hydrocarbon-based molecular cage: The impact of structural rigidity on dynamics, stability, and electronic properties. J. Am. Chem. Soc. 142, 12730–12742 (2020).
